Chirality in liquid crystals: From microscopic origins to macroscopic structure

Chirality in Liquid Crystals: From Microscopic Origins to Macroscopic Structure

Molecular chirality leads to a wonderful variety of equilibrium structures, from the simple cholesteric phase to the twist-grain-boundary phases, and it is responsible for interesting and technologically important materials like ferroelectric liquid crystals. This paper will review some recent advances in our understanding of the connection between the chiral geometry of individual molecules an...

Chirality in Liquid Crystals

Polar liquid crystals in two spatial dimensions: the bridge from microscopic to macroscopic modeling.

Two-dimensional polar liquid crystals have been discovered recently in monolayers of anisotropic molecules. Here, we provide a systematic theoretical description of liquid-crystalline phases for polar particles in two spatial dimensions. Starting from microscopic density functional theory, we derive a phase-field-crystal expression for the free-energy density that involves three local order-par...

From microscopic theory to macroscopic theory: a systematic study on static modeling for liquid crystals

In this paper, we propose a systematic way of liquid crystal modeling to build connection between microscopic theory and macroscopic theory. A new Q-tensor theory based on Onsager’s molecular theory which leads to liquid crystals with certain shape has been proposed. Making uniaxial assumption, we can recover the Oseen-Frank theory from the derived Q-tensor theory, and the Oseen-Frank model coe...

Macroscopic chirality of a liquid crystal from nonchiral molecules.

The transfer of chirality from nonchiral polymer networks to the racemic B2 phase of nonchiral banana-shaped molecules is demonstrated. This corresponds to the transfer of chirality from an achiral material to another achiral material. There are two levels of chirality transfers. (a) On a microscopic level the presence of a polymer network (chiral or nonchiral) favors a chiral state over a ther...